@LuckyBlackCat You certainly can, but it seems like most of our characters will be staying in Windshire the first night so it might be best to wait until the morning.
Also, I'm sure someone will get some amusement from Rheese getting half-suffocated by a Cottonee.
I was thinking of getting the Staryu in Windshire by the sea, is that ok? And yeah, it won't be until the next day, Sophia's not really up to looking for more Pokemon right now.